CHEM 3005 Advanced Physical Chemistry
Credit Points 10
Legacy Code 300926
Coordinator Allan Torres Opens in new window
Description Advanced Physical Chemistry builds on the fundamental principals of energy changes in systems (thermodynamics), and the rates and mechanisms of reactions (kinetics) learnt in Physical Chemistry and extends this so that students gain an understanding of polymer and surface chemistries. This unit also will strengthen student's problem solving skills in quantitative chemical analysis , develop experimental techniques and advanced data-analysis skills.
Discipline Chemical Sciences, Not Elsewhere Classified.
Student Contribution Band HECS Band 2 10cp
Check your HECS Band contribution amount via the Fees page.
Level Undergraduate Level 3 subject
Pre-requisite(s) CHEM 2010
Equivalent Subjects CHEM 3015 - Physical Chemistry 3
An understanding of and competence with the basic principles of physical chemistry including states and properties of matter, thermodynamics, chemical equilibria, kinetics and electrochemistry.
- Demonstrate enhanced laboratory skills, with a particular emphasis on occupational health and safety, risk assessments and the careful and systematic collection of numerical data.
- Analyse numerical problems in physical chemistry, including the use of precision estimates.
- Demonstrate the use of mathematical models for a range of applications in physical chemistry.
- Apply the theory of synthetic, mechanistic, thermodynamic, kinetic and material properties to polymer and surface chemistries in research and industry.
- Apply the theory of physical chemistry to practical applications in other disciplines or subdisciplines; for example, analytical, industrial and environmental chemistry, geochemistry, nanotechnology, biochemistry.
2. Principles of surface thermodynamics: surface tension, contact angles, capillary condensation and rise, Gibbs surface free energy, and surface excess, micelle formation, thermodynamic behaviour of bubbles, droplets, and crystallites.
3. Interfacial properties: adhesion, and spreading, adsorption (chemisorption and physisorption) models for adsorption.
4. Surface characterization by AFM, STM, nanomanipulation.
5. Applications of surface chemistry in industry and the environment.
6. Theory of polymer nomenclature, three dimensional structure, molecular weight and distributions.
7. Stepwise polymerisation: mechanism, kinetics, control of molecular weight distribution.
8. Chain polymerisation: free radical, ionic and coordination mechanisms and kinetics.
9. Control of molecular weight distributions.
10. Chain copolymerisation: copolymerisation kinetics, production of random, alternating, block and graft copolymers.
11. Polymerisation processes and processing.
12. Polymer characterization: GPC, DSC, FTIR, NMR.
13. Introduction to Quantum Chemistry
The following table summarises the standard assessment tasks for this subject. Please note this is a guide only. Assessment tasks are regularly updated, where there is a difference your Learning Guide takes precedence.
|Written Assignment - calculations and analysis, take home||Up to 1,000 words||30||N||Individual|
|Practical - 4 experiments - calculations and brief analysis of data, reports, experiments completed in pairs, individual reports||4 x excel spreadsheets, 2 pages each||30||Y||Individual|
|Final Exam - short answers, problem solving||3 hours||40||Y||Individual|
Parramatta - Victoria Rd
Subject Contact Allan Torres Opens in new window